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By Cotton F., Wilkinson G., Murillo C., Bochmann M.

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H. Mitchell, in C. Kemball, D. A. ): Catalysis, Specialist Periodical Reports, Royal Society of Chemistry, London, Vol. 4, p. 175 (1981). H. Topsøe, B. S. Clausen: Catal. -Sci. Eng. 26, 395 (1984). M. Zdrazil: Catalysis Today 3, 269 (1988). R. Prins, V. H. J. de Beer, G. A. Somorjai: Catal. -Sci. Eng. 31, 1 (1989). B. Delmon: Stud. Surf. Sci. Catal. 53, 1 (1990). M. J. Girgis, B. C. Gates: Ind. Eng. Chem. Res. 30, 2021 (1991). A. N. Startsev: Catal. -Sci. Eng. 37, 353 (1995). H. Topsøe, B. S. Clausen, F.

COORDINATION AND ACTIVATION OF THIOPHENES 41 NMR measurements of the equilibrium constants for a series of ruthenium complexes (Eq. 3) have been performed by Angelici [44], showing that increased methylation on the thiophene results in stronger binding to the metal center and that steric effects are important for the stability of the complexes. and complexes are also more stable than their T analogues. Tetrahydrothiophene (THT) was found to bind times more strongly than thiophene. This is interesting in that it is in parallel with trends previously reported for the adsorption and desulfurization of thiophenes on catalysts [44].

Isoda and I. Mochida: Pap. Am. Chem. Prepr. Div. Petrol. Chem. 39, 622 (1994). G. H. Singhal, R. L. Espino, J. E. Sobel and G. A. Huff: J. Catal. 67, 457 (1981). G. Perot: Catal. Today 10, 447 (1991). S. Kasztelan, T. Des Courières and M. Breysse: Catal. Today 10, 433 (1991). R. M. Laine: Catal. -Sci. Eng. 25, 459 (1983). T. C. Ho: Catal. -Sci. Eng. 30, 117 (1988). J. R. Katzer and R. Sivasubramanian: Catal. -Sci. Eng. 20, 155 (1979). R. Prins, M. Jian and M. Flechsenhar: Polyhedron 16, 3235 (1997).

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